Multimedia

 

Images (Click the thumb to view image)
 
Figure 1: Two-dimensional feature with overhang. The quad-tree mesh is constructed so the cells are concentrated around the interface.
 
Figure 2: Growth rate versus view factor for growth of silicon from silane (SiH4) and SiH2. The growth rate of the feature surface (Figure 1) is shown as a function of the view factor that the surface has with the reactor. Where the view factor equals zero, the feature surface has no line-of-sight view of the reactor, e.g. at a point in the corner under the overhang in Figure 1. Conversely, at a point where the view factor equals one, the feature surface has a line-of-sight view at the only reactor, e.g. a point on top
 
Figure 3: Successive contours of the feature surface as silicon is deposited from pure silane. Deposition is very uniform. As a result, a large void is formed when the feature closes off at the top.
 
Figure 4: Deposition of silicon dioxide (SiO2) from Tetraethoxysilane (TEOS) into a pin-joint feature. Note the relatively uniform thickness of the deposited film.
 

Figure 5: Cryo Scanning Electron Micrograph (SEM) of SiO2 deposited from TEOS into a pin-joint; cf. the theoretical prediction in Figure 4. Note that the film under the overhang is thinner than on than on the top. i.e. it is not uniform. Note also that the bulbous features on the sides of the pin joint are a result of depositing SiO2 on top of SiO2 left over from a previous step and NOT from the non-uniform film growth.

 
Figure 6: Deposition of SiO2 from TEOS into a region between two pin-joint features (cf. Figure 4)
 
Figure 7: CryoSEM if SiO2 film deposited between two pin-joint features (cf. Figure 6)
 
 
Movies (Click the thumb to view movies)
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Movie 1: Deposition of polycrystalline silicon from 100% silane into a circular hub feature.
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Movie 2: Deposition of polycrystalline silicon from a mixture of 99.9% mol silane and 0.1% mol SiH2. Note the profound difference in uniformity from that seen in Movie 1.
   

 

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